LIQUID MIXED METAL STABILISERS

They are essentially Ba-Zn and Ca-Zn + costabilisers liquid systems.

Applications
Composition & Benefits

Risk Assessment

Production break down

Applications

The liquid metal stabilisers are used in several PVC flexible applications, like:

- Calendered fim
- injection moulded footwear
- extruded tubing (garden hoses)
- plastisols (coated fabrics, toys)


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Composition & Benefits

The majority of Ba-Zn stabiliser systems are liquid mixed metal soaps which have similarities to some Ca-Zn stabilisers and are generally in the form of a carboxylate. As in the case of Ca-Zn heat stabilisers, all of these products require the addition of co-stabilisers to provide optimum performance. These are the same type of products as are used with Ca-Zn stabilisers. Solvents are sometimes incorporated. These stabilisers have successfully replaced Cadmium based stabilisers in many applications.

The stabilisers are formulated to suit specific requirements such as clarity, good initial colour, long-term stability and compatibility with filled, pigmented systems. Some products achieve a good compromise of all the necessary requirements while others are designed to meet only one or two.

A group of specialised liquid soaps allied to Ba-Zn soaps are Zinc or Potassium-Zinc soaps. These are generally laurates or octoates and are used as PVC stabilisers and as activators (or "kickers") for the blowing agent used in making the foamed layer in a number of plastisol applications.


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