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Stabilisers types
The main types of stabiliser systems
are based either on lead, mixed metals (principally barium/zinc
or calcium/zinc), tin or cadmium, although use of cadmium systems
is currently being phased out in Europe.
Approximately 170,000 tons of stabilisers
are used in Europe every year. The type of product used breaks
down as follows:
(2000 Industry Figures)
Selection of the appropriate variety
was initially founded upon empirical grounds. Because of the vast
variety of uses of PVC in society, and because of the complexity
of processes and application, the selection of the appropriate
stabiliser system requires considerable knowledge and expertise
of process equipment polymer choice and final application.
Chemically, the stabiliser functions
by reacting with any chlorine (in radical or hydrochloric acid
form) freed during the thermal stress of processing or use. Light-induced
degradation is more complex and the protective effect of stabilisers
can be reinforced with specific UV-stabilisers.
To suit the needs of a particular
application, a stabiliser "one-pack" is often formulated,
including one or more of the above products. The one-pack often
includes a mixture of internal- and external lubricants and other
processing aids, based on extensive industry know-how. In addition,
plasticisers, pigments, fillers, impact modifiers and other additives
are used to customise PVC to specific end-uses.
To learn more about the main categories
of PVC stabilisers click on your selection to the left.
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